The team’s results are important because they demonstrate that the magnetic moments (the measure of the strength of a magnetic source) of a large number of atoms can band together to form quantum states much like those of a very large molecule. Though, on the surface, these atomic “compass needles” seem to be disorganized and disordered, the team was able to discern “a beautiful, underlying quantum order,” said team member Collin Broholm, professor in the Henry A. Rowland Department of Physics and Astronomy at Johns Hopkins’ Krieger School of Arts and Sciences.
“Quantum mechanics is normally appreciated only on the atomic scale. However, here we present evidence for a very long and very quantum mechanical magnetic molecule,” Broholm said. “While disordered to a classical observer, the magnetic moments of almost 100 nickel atoms arranged in a row within a solid were shown to display an underlying quantum coherence limited only by chemical and thermal impurities. The progress we made is really a demonstration of quantum coherence among a larger number of atoms in a magnet than ever before.”
In addition, the team has established the factors that affect the distance over which the hidden “quantum order” can be maintained.
That distance, as well as how it changes as a result of heating and chemical impurities in the material, may well prove to be essential in determining whether the material will have practical applications.
The team studied a ceramic material consisting of chains of nickel-centered oxygen octahedra laid end-to-end. The chains are not ordinary magnets such as people use to tack reminders onto refrigerator doors; instead, they are an exotic, quantum spin liquid in which electron spins (analogous to tiny bar magnets) point in random directions with no particular order, even at very low temperatures.
To measure the quantum order through this classically disordered liquid, scientists used neutrons to image the magnetic excitations – also called “flips” – and the distances over which they could propagate. The experiments were performed at the National Institute of Standards and Technology Center for Neutron Research in the United States and at the ISIS particle accelerator of the Rutherford Appleton Laboratory in the United Kingdom. |
